Thermodynamics properties of NiCuP4O12
Identifieur interne : 000572 ( Main/Exploration ); précédent : 000571; suivant : 000573Thermodynamics properties of NiCuP4O12
Auteurs : M. Belaiche [Maroc] ; M. Bakhache [Maroc] ; M. Benhammou [Maroc] ; K. El-Mabrouke [Canada] ; M. Bousmina [Maroc, Canada]Source :
- Physica. E, low-dimentional systems and nanostructures [ 1386-9477 ] ; 2008.
Descripteurs français
- Pascal (Inist)
English descriptors
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Abstract
The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF = -1.125 K.
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Belaiche</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235</s1><s2>Ocean, Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Hassan II Academy of Science and Technology</s1><s2>Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation></author><author><name sortKey="Bakhache, M" sort="Bakhache, M" uniqKey="Bakhache M" first="M." last="Bakhache">M. Bakhache</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratory of Magnetism, Magnetic Materials, Micro-waves and Ceramics, Ecole Normale Supérieure de Rabat, BP 9235</s1><s2>Ocean, Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation></author><author><name sortKey="Benhammou, M" sort="Benhammou, M" uniqKey="Benhammou M" first="M." last="Benhammou">M. 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Bousmina</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Hassan II Academy of Science and Technology</s1><s2>Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Canada Research Chair on Polymer Physics and Nanomaterials, Department of Chemical Engineering (CREPEC), Laval University</s1><s2>Sainte-Foy, Que., GIK 7P4</s2><s3>CAN</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Canada</country><wicri:noRegion>Sainte-Foy, Que., GIK 7P4</wicri:noRegion></affiliation></author></analytic><series><title level="j" type="main">Physica. E, low-dimentional systems and nanostructures</title><title level="j" type="abbreviated">Physica ( E) low-dimens. syst. nanostrut.</title><idno type="ISSN">1386-9477</idno><imprint><date when="2008">2008</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Physica. E, low-dimentional systems and nanostructures</title><title level="j" type="abbreviated">Physica ( E) low-dimens. syst. nanostrut.</title><idno type="ISSN">1386-9477</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alternated chains model</term><term>Anisotropy</term><term>Antiferromagnetism</term><term>Exchange interactions</term><term>Ferromagnetism</term><term>Magnetic ordering</term><term>Magnetic susceptibility</term><term>Specific heat</term><term>Spin chain</term><term>Thermodynamic properties</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Propriété thermodynamique</term><term>Susceptibilité magnétique</term><term>Chaleur massique</term><term>Chaîne spin</term><term>Ordre magnétique</term><term>Anisotropie</term><term>Interaction échange</term><term>Ferromagnétisme</term><term>Antiferromagnétisme</term><term>Modèle chaîne alternée</term><term>CuNiP4O12</term><term>Phosphate de cuivre et de nickel</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP<sub>4</sub>O<sub>12</sub>) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant J<sub>F</sub> = 4.05K, with a significant effect of single ion anisotropy D = 9.70K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2z<sub>AF</sub>J<sub>AF</sub> = -1.125 K.</div></front></TEI><affiliations><list><country><li>Canada</li><li>Maroc</li></country><region><li>Rabat-Salé-Kénitra</li></region><settlement><li>Rabat</li></settlement></list><tree><country name="Maroc"><region name="Rabat-Salé-Kénitra"><name sortKey="Belaiche, M" sort="Belaiche, M" uniqKey="Belaiche M" first="M." last="Belaiche">M. Belaiche</name></region><name sortKey="Bakhache, M" sort="Bakhache, M" uniqKey="Bakhache M" first="M." last="Bakhache">M. Bakhache</name><name sortKey="Belaiche, M" sort="Belaiche, M" uniqKey="Belaiche M" first="M." last="Belaiche">M. Belaiche</name><name sortKey="Benhammou, M" sort="Benhammou, M" uniqKey="Benhammou M" first="M." last="Benhammou">M. Benhammou</name><name sortKey="Bousmina, M" sort="Bousmina, M" uniqKey="Bousmina M" first="M." last="Bousmina">M. Bousmina</name></country><country name="Canada"><noRegion><name sortKey="El Mabrouke, K" sort="El Mabrouke, K" uniqKey="El Mabrouke K" first="K." last="El-Mabrouke">K. El-Mabrouke</name></noRegion><name sortKey="Bousmina, M" sort="Bousmina, M" uniqKey="Bousmina M" first="M." last="Bousmina">M. Bousmina</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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